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3.戊基(C5H11-):戊基是5-Azido-1-pentanol的主链,它决定了分子的整体结构和性质。 戊基链的长度适中,既保证了分子的稳定性,又使得分子具有一定的灵活性,有利于与其他化合物发生反应。
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(记住一些常见的取代基的异构体数目,可快速确定同分异构体的数目:-C3H7有2种,-C4H9有4种,-C5H11有8种。 ) 替代法:如二氯苯 (C6H4Cl2)有三种同分异构体,四氯苯也有三种同分异构体;又如CH4的一氯代物只有一种,新戊烷 [C (CH3)4]的一氯代物也只有一种。
③戊基的结构有8种,则一氯戊烷 (C5H11—Cl)、戊醇 (C5H11—OH)、己醛 (C5H11—CHO)、己酸 (C5H11—COOH)有8种同分异构体。 (3)先定后动法 分析二元取代物的方法,如分析C3H6Cl2的同分异构体,先固定其中一个Cl的位置,移动另外一个Cl,从而得到其同分异构体,共四种。
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Kinetics, equilibrium, and negative temperature dependence in the bimolecular reaction tert-C4H9+ (iso-C5H12, iso-C4H10) tert-C5H11+ between 190 and 5700K J. J. Solomon ...
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