As a quick note, these aren't games that are only on PS5 - you want our best PS5 exclusives list for those games and their brethren - but rather the best ones you can play on PS5 more broadly ...
That's a total of 56 games, with two being exclusive to PSVR 2. Although a few of these were already confirmed to be part of the PS5 Pro enhanced library by Sony, there is some new information here.