A picket-fence porphyrin complex of Fe, with axial coordination sites occupied by methylimidazole (green) and dioxygen (R = amide groups). [6] ...

Neurotransmitters are key for synaptic transmission at axon terminals, but their transport modalities remain debated. This ...

The coupling of rR spectroscopy with cryoradiolysis method, which involves γ-irradiation of the freeze-trapped dioxygen adducts, provides an effective method to generate, trap and structurally ...

A group of researchers has developed an electrocatalyst that promises to significantly enhance the efficiency and stability of oxygen evolution reactions (OER) in acidic environments. By ...

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A major project focuses on the particulate, membrane-bound methane monooxygenase (pMMO), with emphasis on elucidating the atomic details of the copper active site, understanding the mechanisms of ...

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Metal peroxides are metal-containing compounds with ionically- or covalently-bonded peroxide (O 2− ...

Our recent studies of catalytic intermediates that form during the activation of dioxygen by heme enzymes (eg. P450; heme oxygenase) and during the reduction of dinitrogen by nitrogenase have been ...