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综述:甲酸配体:金属有机框架中金属氧化物簇节点 ...
甲酸(formic acid)衍生的甲酸配体(formate)因其与MOF常见羧酸配体的结构相似性,成为解码节点化学的“分子钥匙”。 甲酸配体在MOF节点上的证据 2014年Yaghi团队首次在MOF-808合成中发现甲酸配体占据Zr 6 O 8 节点的结构空位,并通过 1 H NMR定量其数量。
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